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NR 440.56(6)(a)1. 1. Analysis using Method 24A of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1) of routine weekly samples of raw ink and related coatings in each respective storage tank.
NR 440.56(6)(a)2. 2. Analysis using Method 24A of Appendix A of samples of each shipment of all purchased raw inks and related coatings.
NR 440.56(6)(a)3. 3. Determination of the VOC content from the formulation data supplied by the ink manufacturer with each shipment of raw inks and related coatings used.
NR 440.56(6)(b) (b) The owner or operator of any affected facility using solventborne ink systems shall use the results of verification analyses by Method 24A of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), to determine compliance when discrepancies with ink manufacturers' formulation data occur.
NR 440.56(6)(c) (c) The owner or operator of any affected facility using waterborne ink systems shall determine the VOC and water content of raw inks and related coatings used at the affected facility by either:
NR 440.56(6)(c)1. 1. Determination of the VOC and water content from the formulation data supplied by the ink manufacturer with each shipment of purchased raw inks and related coatings used; or
NR 440.56(6)(c)2. 2. Analysis of samples of each shipment of purchased raw inks and related coatings using a test method approved by the department in accordance with s. NR 440.08 (2).
NR 440.56(6)(d) (d) The owner or operator of any affected facility shall determine the density of raw inks, related coatings and VOC solvents by one of the following:
NR 440.56(6)(d)1. 1. Making a total of 3 determinations for each liquid sample at specified temperatures using the procedure outlined in ASTM D1475-90, incorporated by reference in s. NR 440.17 (2) (a) 19. The temperature and density shall be recorded as the arithmetic average of the 3 determinations.
NR 440.56(6)(d)2. 2. Using literature values, at specified temperatures, acceptable to the department.
NR 440.56(6)(e) (e) If compliance is determined according to sub. (4) (e), (f) or (g), the existing as well as affected facilities are subject to the requirements of pars. (a) through (d).
NR 440.56 History History: Cr. Register, January, 1984, No. 337, eff. 2-1-84; am. (2) (a) (intro.), Register, September, 1990, No. 417, eff. 10-1-90; cr. (2) (b) 10m., Register, May, 1993, No. 450, eff. 8-1-93; correction in (4) made under s. 13.93 (2m) 1., Stats., Register, November, 1999, No. 527; CR 06-109: am. (2) (b) 1. to 25. and (c) 1. to 4., (4) (a) 5. (intro.), a., c. and d., (6) (a) 1. and 2., (b) and (d) (intro.) and 1. Register May 2008 No. 629, eff. 6-1-08.
NR 440.565 NR 440.565Pressure sensitive tape and label surface coating operations.
NR 440.565(1) (1)Applicability and designation of affected facility.
NR 440.565(1)(a)(a) The affected facility to which the provisions of this section apply is each coating line used in the manufacture of pressure sensitive tape and label materials.
NR 440.565(1)(b) (b) Any affected facility which inputs to the coating process 45 Mg (50 tons) of VOC or less per 12-month period is not subject to the emission limits of sub. (3) (a), however, the affected facility is subject to the requirements of all other applicable subsections of this section. If the amount of VOC input exceeds 45 Mg (50 tons) per 12-month period, the coating line will become subject to sub. (3) (a) and all other subsections of this section.
NR 440.565(1)(c) (c) This section applies to any affected facility which begins construction, modification, or reconstruction after December 30, 1980.
NR 440.565(2) (2)Definitions and symbols.
NR 440.565(2)(a)(a) As used in this section, terms not defined in this subsection have the meanings given in s. NR 440.02, unless the context requires otherwise.
NR 440.565(2)(a)1. 1. “Coating line" means any number or combination of adhesive, release, or precoat coating applicators, flashoff areas and ovens which coat a continuous web, located between a web unwind station and a web rewind station, to produce pressure sensitive tape and label materials.
NR 440.565(2)(a)3. 3. “Coating solids applied" means the solids content of the coated adhesive, release, or precoat as measured by Method 24 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1).
NR 440.565(2)(a)4. 4. “Flashoff area" means the portion of a coating line after the coating applicator and usually before the oven entrance.
NR 440.565(2)(a)5. 5. “Fugitive volatile organic compounds" means any volatile organic compounds which are emitted from the coating applicator and flashoff areas and are not emitted in the oven.
NR 440.565(2)(a)6. 6. “Hood or enclosure" means any device used to capture fugitive volatile organic compounds.
NR 440.565(2)(a)7. 7. “Oven" means a chamber which uses heat or irradiation to bake, cure, polymerize, or dry a surface coating.
NR 440.565(2)(a)8. 8. “Precoat" means a coating operation in which a coating other than an adhesive or release is applied to a surface during the production of a pressure sensitive tape or label product.
NR 440.565(2)(a)9. 9. “Solvent applied in the coating" means all organic solvent contained in the adhesive, release and precoat formulations that is metered into the coating applicator from the formulation area.
NR 440.565(2)(a)10. 10. “Total enclosure" means a structure or building around the coating applicator and flashoff area or the entire coating line for the purpose of confining and totally capturing fugitive VOC emissions.
NR 440.565(2)(a)11. 11. “VOC" means volatile organic compound.
NR 440.565(2)(b) (b) As used in this section, symbols not defined in this subsection have the meanings given in s. NR 440.03.
NR 440.565(2)(b)1. 1. “a" means the gas stream vents exiting the emission control device.
NR 440.565(2)(b)2. 2. “b" means the gas stream vents entering the emission control device.
NR 440.565(2)(b)3. 3. “C aj" means the concentration of VOC (carbon equivalent) in each gas stream (j) exiting the emission control device, in parts per million by volume.
NR 440.565(2)(b)4. 4. “C bi" means the concentration of VOC (carbon equivalent) in each gas stream (i) entering the emission control device, in parts per million by volume.
NR 440.565(2)(b)5. 5. “C fk" means the concentration of VOC (carbon equivalent) in each gas stream (k) emitted directly to the atmosphere, in parts per million by volume.
NR 440.565(2)(b)6. 6. “G" means the calculated weighted average mass (kg) of VOC per mass (kg) of coating solids applied each calendar month.
NR 440.565(2)(b)7. 7. “M ci" means the total mass (kg) of each coating (i) applied during the calendar month as determined from facility records.
NR 440.565(2)(b)8. 8. “M r" means the total mass (kg) of solvent recovered for a calendar month.
NR 440.565(2)(b)9. 9. “Q aj" means the volumetric flow rate of each affluent gas stream (j) exiting the emission control device, in dry standard cubic meters per hour.
NR 440.565(2)(b)10. 10. “Q bi" means the volumetric flow rate of each effluent gas stream (i) entering the emission control device, in dry standard cubic meters per hour.
NR 440.565(2)(b)11. 11. “Q fk" means the volumetric flow rate of each effluent gas stream (k) emitted to the atmosphere, in dry standard cubic meters per hour.
NR 440.565(2)(b)12. 12. “R" means the overall VOC emission reduction achieved for a calendar month (in percent).
NR 440.565(2)(b)13. 13. “R q" means the required overall VOC emission reduction (in percent).
NR 440.565(2)(b)14. 14. “W oi" means the weight fraction of organics applied of each coating (i) applied during a calendar month as determined from Method 24 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), or coating manufacturer's formulation data.
NR 440.565(2)(b)15. 15. “W si" means the weight fraction of solids applied of each coating (i) applied during a calendar month as determined from Method 24 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), or coating manufacturer's formulation data.
NR 440.565(3) (3)Standard for volatile organic compounds.
NR 440.565(3)(a)(a) On and after the date on which the performance test required by s. NR 440.08 has been completed each owner or operator subject to this section may:
NR 440.565(3)(a)1. 1. Cause the discharge into the atmosphere from an affected facility not more than 0.20 kg VOC/kg of coating solids applied as calculated on a weighted average basis for one calendar month; or
NR 440.565(3)(a)2. 2. Demonstrate for each affected facility;
NR 440.565(3)(a)2.a. a. A 90% overall VOC emission reduction as calculated over a calendar month; or
NR 440.565(3)(a)2.b. b. The percent overall VOC emission reduction specified in sub. (4) (b) as calculated over a calendar month.
NR 440.565(4) (4)Compliance provisions.
NR 440.565(4)(a)(a) To determine compliance with sub. (3) the owner or operator of the affected facility shall calculate a weighted average of the mass of solvent used per mass of coating solids applied for one calendar month period according to the following procedures:
NR 440.565(4)(a)1. 1. Determine the weight fraction of organics and the weight fraction of solids of each coating applied by using Reference Method 24 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17, or by the coating manufacturer's formulation data.
NR 440.565(4)(a)2. 2. Compute the weighted average by the following equation: - See PDF for diagram PDF
NR 440.565(4)(a)3. 3. For each affected facility where the value of G is less than or equal to 0.20 kg VOC per kg of coating solids applied the affected facility is in compliance with sub. (3) (a) 1.
NR 440.565(4)(b) (b) To determine compliance with sub. (3) (a) 2. the owner or operator shall calculate the required overall VOC emission reduction according to the following equation: - See PDF for diagram PDF
If Rq is less than or equal to 90% the required overall VOC emission reduction is Rq. If Rq is greater than 90% the required overall VOC emission reduction is 90%.
NR 440.565(4)(c) (c) Where the compliance with the emission limits specified in sub. (3) (a) 2. is achieved through the use of a solvent recovery system the owner or operator shall determine the overall VOC emission reduction for a one calendar month period by the following equation: - See PDF for diagram PDF
If the R value is equal to or greater than the Rq value specified in par. (b) compliance with sub. (3) (a) 2. is demonstrated.
NR 440.565(4)(d) (d) Where compliance with the emission limit specified in sub. (3) (a) 2. is achieved through the use of a solvent destruction device the owner or operator shall determine calendar monthly compliance by comparing the monthly required overall VOC emission reduction specified in par. (b) to the overall VOC emission reduction demonstrated in the most recent performance test which complied with sub. (3) (a) 2. If the monthly required overall VOC emission reduction is less than or equal to the overall VOC reduction of the most recent performance test the affected facility is in compliance with sub. (3) (a) 2.
NR 440.565(4)(e) (e) Where compliance with sub. (3) (a) 2. is achieved through the use of a solvent destruction device, the owner or operator shall continuously record the destruction device combustion temperature during coating operations for thermal incineration destruction devices or the gas temperature upstream and downstream of the incinerator catalyst bed during coating operations for catalytic incineration destruction devices. For thermal incineration destruction devices the owner or operator shall record all 3-hour periods (during actual coating operations) during which the average temperature of the device is more than 28°C (50°F) below the average temperature of the device during the most recent performance test complying with sub. (3) (a) 2. For catalytic incineration destruction devices, the owner or operator shall record all 3-hour periods (during actual coating operations) during which the average temperature of the device immediately before the catalyst bed is more than 28°C (50°F) below the average temperature of the device during the most recent performance test complying with sub. (3) (a) 2. and all 3-hour periods (during actual coating operations) during which the average temperature difference across the catalyst bed is less than 80% of the average temperature difference of the device during the most recent test complying with sub. (3) (a) 2.
NR 440.565(4)(f) (f) After the initial performance test required for all affected facilities under s. NR 440.08, compliance with the VOC emission limitation and percentage reduction requirements under sub. (3) is based on the average emission reduction for one calendar month. A separate compliance test is completed at the end of each calendar month after the initial performance test and a new calendar month's average VOC emission reduction is calculated to show compliance with the standard.
NR 440.565(4)(g) (g) If a common emission control device is used to recover or destroy solvent from more than one affected facility the performance of that control device is assumed to be equal for each of the affected facilities. Compliance with sub. (3) (a) 2. is determined by the methods specified in pars. (c) and (d) and is performed simultaneously on all affected facilities.
NR 440.565(4)(h) (h) If a common emission control device is used to recover solvent from an existing facility (or facilities) as well as from an affected facility (or facilities) the overall VOC emission reduction for the affected facility (or facilities) for the purpose of compliance, shall be determined by the following procedures:
NR 440.565(4)(h)1. 1. The owner or operator of the existing facility (or facilities) shall determine the mass of solvent recovery for a calendar month period from the existing facility (or facilities) prior to the connection of the affected facility (or facilities) to the emission control device.
NR 440.565(4)(h)2. 2. The affected facility (or facilities) shall then be connected to the emission control device.
NR 440.565(4)(h)3. 3. The owner or operator shall determine the total mass of solvent recovery from both the existing and affected facilities over a calendar month period. The mass of solvent determined in subd. 1. from the existing facility shall be subtracted from the total mass of recovery solvent to obtain the mass of solvent recovery from the affected facility (or facilities). The overall VOC emission reduction of the affected facility (or facilities) can then be determined as specified in par. (c).
NR 440.565(4)(i) (i) If a common emission control device is used to destruct solvent from an existing facility (or facilities) as well as from an affected facility (or facilities) the overall VOC emission reduction for the affected facility (or facilities), for the purpose of compliance, shall be determined by the following procedures:
NR 440.565(4)(i)1. 1. The owner or operator shall operate the emission control device with both the existing and affected facilities connected.
NR 440.565(4)(i)2. 2. The concentration of VOC (in parts per million by volume) after the common emission control device shall be determined as specified in sub. (5) (c).
NR 440.565(4)(j) (j) Startups and shutdowns are normal operation for this source category. Emissions from these operations are to be included when determining if the standard specified at sub. (3) (a) 2. is being attained.
NR 440.565(5) (5)Performance test procedures.
NR 440.565(5)(a)(a) The performance test for affected facilities complying with sub. (3) without the use of add-on controls shall be identical to the procedures specified in sub. (4) (a).
NR 440.565(5)(b) (b) The performance test for affected facilities controlled by a solvent recovery device shall be conducted as follows:
NR 440.565(5)(b)1. 1. The performance test shall be a one calendar month test and not the average of 3 runs as specified in s. NR 440.08 (6).
NR 440.565(5)(b)2. 2. The weighted average mass of VOC per mass of coating solids applied for a one calendar month period shall be determined as specified in sub. (4) (a) 2.
NR 440.565(5)(b)3. 3. Calculate the required percent overall VOC emission reduction as specified in sub. (4) (b).
NR 440.565(5)(b)4. 4. Inventory VOC usage and VOC recovery for a one calendar month period.
NR 440.565(5)(b)5. 5. Determine the percent overall VOC emission reduction as specified in sub. (4) (c).
NR 440.565(5)(c) (c) The performance test for affected facilities controlled by a solvent destruction device shall be conducted as follows:
NR 440.565(5)(c)1. 1. The performance of the solvent destruction device shall be determined by averaging the results of 3 test runs as specified in s. NR 440.08 (6).
NR 440.565(5)(c)2. 2. Determine for each affected facility prior to each test run the weighted average mass of VOC per mass of coating solids applied being used at the facility. The weighted average shall be determined as specified in sub. (4) (a). In this application the quantities of Woi, Wsi and Mci shall be determined for the time period of each test run and not a calendar month as specified in sub. (2).
NR 440.565(5)(c)3. 3. Calculate the required percent overall VOC emission reduction as specified in sub. (4) (b).
NR 440.565(5)(c)4. 4. Determine the percent overall VOC emissions reduction of the solvent destruction device by the following equation and procedures: - See PDF for diagram PDF
NR 440.565(5)(c)4.a. a. The owner or operator of the affected facility shall construct the overall VOC emission reduction system so that all volumetric flow rates and total VOC emissions can be accurately determined by the applicable test methods and procedures specified in sub. (7) (b).
NR 440.565(5)(c)4.b. b. The owner or operator of an affected facility shall construct a temporary total enclosure around the coating line applicator and flashoff area during the performance test for the purpose of capturing fugitive VOC emissions. If a permanent total enclosure exists in the affected facility prior to the performance test and the department is satisfied that the enclosure is totally capturing fugitive VOC emissions then no additional total enclosure will be required for the performance test.
NR 440.565(5)(c)4.c. c. For each affected facility where the value of R is greater than or equal to the value Rq calculated in sub. (4) (b) compliance with sub. (3) (a) 2. is demonstrated.
NR 440.565(6) (6)Monitoring of operations and recordkeeping.
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Published under s. 35.93, Stats. Updated on the first day of each month. Entire code is always current. The Register date on each page is the date the chapter was last published.